Selected Publications of Mr. Xiqu Wang
PATENTS
Xiqu Wang, Lumei Liu
and Allan J. Jacobson, 2008,
MICROPOROUS CRYSTALLINE METAL SILICATES
AND
PROCESSES FOR THEIR PREPARATION. US Patent, 7314605.
Allan J.
Jacobson, Lumei Liu, Xiqu
Wang, 2012,
Porous solids, selective separations, removal
of sulfur compounds, adsorption. US Patent, 8293133.
ARTICLES
Wang, X.; Makarenko, T.; Makarenko, B.; Jacobson, A.
J., 2012, Synthesis and structures
of two open-framework manganese phosphate-silicates,
Zeitschrift fuer Kristallographie - Crystalline Materials, 227, 489-493.
Gao, Q.; Wang, X.; Jacobson, A. J., 2012,
A homochiral diamond framework constructed
from
Fe(III) and Mn(II) oxo-clusters
supported by Sb(III) tartrate
scaffolds.
Gao, Q.; Wang, X.; Conato, M. T.;
Makarenko, T.; Jacobson, A. J., 2011, Homochiral
structures
containing
iron oxo-clusters supported by antimony(III) tartrate scaffolds,
Crystal Growth &
Design, 11, 4632-4638.
Wang, X.; Liu, L.; Marlon, C.; Jacobson, A. J., 2011,
Amine-templated anionic
metal-organic
frameworks with the 4,4'-(hexafluoroisopropylidene)
bis(benzoic acid) ligand
Crystal Growth & Design,11, 2257-2263.
Wang, X.; Liu, L.; Eckert, J.; Jacobson, A. J., 2011,
Breathing and twisting: An investigation
of framework deformation and guest packing in
single crystals of a microporous vanadium and
benzenedicarboxylate, Inorganic
Chemistry, 50, 2028–2036.
Liebau, F.; Klein, H.-J.; Wang, X., 2011, A crystal chemical
approach to superconductivity.
I. A bond-valence sum analysis of inorganic compounds,
Zeitschrift fur Kristallography, 226, 309-318.
Wang, X.; Liu, L.; Jacobson, A. J., 2011, Covalently interconnected and
separated vanadosilicate
shells,
Mater.
Res. Soc. Symp. Proc., 1309, 10.1557/opl.2011.105.
Wang, X.; Liu, L.; Makarenko, T.; Jacobson, A. J., 2010,
Influence
of ligand geometry
on the dimensionality of Sn(II) benzenedicarboxylate crystal structures,
Crystal Growth & Design, 10, 3752–3756.
Wang, X.; Liu, L.; Makarenko, T.; Jacobson, A. J., 2010,
Acentric and centric interpenetrations
of an anionic framework mediated by cation
sizes: the alkali-metal tin(II)
benzenedicarboxylates A2Sn2(bdc)3(H2O)x (A = Li, Na, K,
Rb, Cs),
Crystal Growth & Design, 10, 1960–1965.
Liu, L.; Wang, X.; Jacobson, A. J., 2010, AlF·1,4-benzenedicarboxylate: synthesis and
absorption
properties, Dalton
Transactions, 39, 1722–1725.
Kim, I. H.; Wang, X.; Jacobson, A. J., 2010, Open layers based on metal-oxide chains
linked by
cyclohexanedicarboxylate ligands, Solid State Sciences, 12, 76–82.
Gil-Mateo, P.; Wang, X.; Jacobson, A. J., 2009, Synthesis and structures of novel lanthanide
benzenedicarboxylates, Mater. Res. Soc. Symp. Proc., 1148, PP08-02.
Liu, L.; Wang, X.; Jacobson, A. J., 2009, Vanadium (IV) benzenedicarboxylate: A novel
adsorbent for selective separations, Journal of Materials
Research., 24,
1901-1905.
Pesak, R.; Wang, X.; Jacobson, A. J., 2009, Syntheses and structures of
Ta2(WO2)0.87H0.26(PO4)4
and Ta2(MoO2)(PO4)4, Materials Research Bulletin, 44, 688-692.
LeBeau, J. M.; Findlay, S. D.; Wang, X.; Jacobson, A. J.; Allen, L. J.; Stemmer, S., 2009,
High-angle
scattering of fast electrons from crystals containing heavy elements:
Simulation
and experiment, Physical Review B, 79, 214110.
Wang, X.; Liebau, F., 2009, On the optimization of bond-valence parameters:
artifacts conceal
chemical effects.
Acta Crystallographica, Section B: Structural Science,
B65, 96-98.
Liebau, F.; Wang, X., 2009,
Stoichiometric valence and structural valence--two different sides
of the same coin: “bonding power”. Chemistry - A European Journal, 15, 2728-37.
Vougo-Zanda, Anokhina, E. V.; Duhovic,
S.; Liu, L.; Wang, X.; Oloba, O. A.; Albright, T. A.;
Jacobson, A. J., 2008, Octahedral Tilting in MM′X4
Metal-Oxide Organic Layer Structures,
Inorganic Chemistry, 47, 4746-4751.
Vougo-Zanda, M.; Huang, J.; Anokhina, E. V.; Wang, X.; Jacobson, A. J., 2008, Tossing and
Turning: Guests in the Flexible Frameworks of Metal(III) Dicarboxylates. ,
Inorganic Chemistry, 47, 4746-4751.
Liebau, F.; Wang,
X., 2008, A bond-valence
investigation of two series of isostructural
lanthanide .
compounds. Acta
Crystallographica, Section B: Structural Science,
B64(3), 299-304.
Pesak, R.; Wang, X.; Jacobson,
A. J., 2008, Crystal growth of AlPO-5, AlPO-15, and AlPO-21.
from aluminum foil. Microporous and Mesoporous Materials, 109(1-3), 478-484.
Wang, X.; Liebau, F., 2007, Influence of polyhedron distortions on
calculated bond valence sums.
Acta Crystallographica, Section B: Structural Science. B63, 216-228. [PDF]
Vougo-Zanda, M.; Wang, X.; Jacobson, A. J., 2007, Influence of ligand geometry on the
formation of In-O
chains in metal-oxide organic frameworks (MOOFs).
Inorganic Chemistry, 46, 8819-8824..
Go, Y.;Wang, X.; Jacobson, A. J., 2007, (6,3)-Honeycomb
structures of uranium(VI)
benzenedicarboxylate
derivatives: the use of noncovalent interactions to
prevent interpenetration.
Inorganic Chemistry, 46, 6594-6600..
Wang, X.; Liu, L.; Jacobson, A. J., 2006, Intercalation of Organic Molecules into Vanadium(IV)
Benzenedicarboxylate: Adsorbate
Structure and Selective Absorption of Organosulfur
Compounds
Angewandte Chemie Int. Ed., 45, 6499-6503. [PDF]
Wang, X.; Liu, L.; Jacobson, A.
J., 2006, Synthesis and structures of a series of novel
rare earth transition metal sulfates.
Journal of Rare Earths, 24,
659-662.
Wang, X.; Liu, L.; Wang, L.; Jacobson, A. J.,
2005, Hydrothermal synthesis and structures
of the open-framework copper silicates Na2[Cu2Si4O11](H2O)2
(CuSH-2Na),
Na2[CuSi3O8] (CuSH-3Na), Cs2Na4[Cu2Si12O27(OH)2](OH)2
(CuSH-4NaCs), and
Na2[Cu2Si5O13](H2O)3 (CuSH-6Na).
Wang, X.; Liu, L.; Wang, L.; Jacobson, A. J.,
2005, Open framework copper titanosilicates.
.
in Solid-State Chemistry of
Inorganic Materials V, edited by J. Li, N. E. Brese,
M. G. Kanatzidis, M. Jansen (Mater.
Res. Soc. Symp. Proc. 848), 97-102. [PDF]
Liebau, F.; Wang, X., 2005, Stoichiometric
valence versus structural valence: Conclusions
drawn from a study of the influence of polyhedron distortion
on bond valence sums.
Zeitschrift fur Kristallography,
220, 589-591. [PDF]
Wang, X.; Liebau, F., 2005, The contribution to bond valences by lone electron
pairs.
in Solid-State Chemistry of Inorganic
Materials V, edited by J. Li, N. E. Brese,
M. G. Kanatzidis, M. Jansen (Mater.
Res. Soc. Symp. Proc. 848), 345-350. [PDF]
Anokhina, E. V.; Vougo-Zanda, M.; Wang, X.; Jacobson, A. J., 2005, In(OH)BDC.
0.75BDCH2 (BDC = Benzenedicarboxylate), a Hybrid Inorganic-Organic Vernier Structure.
Journal of the American Chemical Society, 127, 15000-15001. [PDF]
Go, Y.; Wang, X.;
Anokhina, E. V.; Jacobson, A. J., 2005, Influence of the Reaction
Temperature and pH
on the Coordination Modes of the 1,4-Benzenedicarboxylate
(BDC) Ligand: A Case Study of the NiII(BDC)/2,2'-Bipyridine
System.
Inorganic Chemistry, 44,
8265-8271. [PDF]
Whitfield, T. R.;
Wang, X.; Liu, L.; Jacobson, A. J., 2005, Metal-organic frameworks
based
on iron oxide
octahedral chains connected by benzenedicarboxylate dianions.
.
Wang, X.; Liu, L.; Huang, J.; Jacobson, A. J., 2004,
Synthesis, structure and properties
of CsHSi3O7, a layered silicate with a chiral structure.
Journal of
Wang, X.; Liu, L.; Jacobson, A. J., 2004,
Hydrothermal synthesis and structures of the novel
niobium phosphates [NbOF(PO4)](N2C5H7)
and [(Nb0.9V1.1)O2(PO4)2
(H2PO4)](N2C2H10).
Journal of
Go, Y.; Wang, X.; Anokhina, E. V.; Jacobson, A. J., 2004, A chain of
changes: influence of
noncovalent interactions on the
one-dimensional structures of nickel(II) dicarboxylate
coordination
polymers with chelating aromatic amine ligands,
Inorganic Chemistry), 43, 5360-5367.
Wang, X.; Liu, L.; Jacobson, A.
J., 2003, Nanoporous copper silicates with
one-dimensional
12-ring channel systems.
Angewandte Chemie, International Edition, 42,
2044-2047. [PDF]
Huang, J.; Wang, X.; Jacobson, A. J., 2003,
Hydrothermal synthesis and structures of
the new open-framework uranyl
silicates Rb4(UO2)2(Si8O20)
(USH-2Rb),
Rb2(UO2)(Si2O6)·H2O
(USH-4Rb) and A2(UO2)(Si2O6)·0.5H2O
(USH-5A; A = Rb, Cs).
Journal of Materials Chemistry, 13, 191-196.
Whitfield, T.; Wang, X.; Zheng,
L.-M.; Jacobson, A. J., 2003, Hydrothermal
synthesis of
germanium vanadate layered compounds.
Journal of
Whitfield, T.; Wang, X.; Jacobson, A. J., 2003, Vanadogermanate
Cluster Anions.
Inorganic Chemistry, 42,
3728-3733.
Hoche, T.; Olhe,
P.; Keding, R.; Russel, C.;
van Aken, P. A.; Schneider, R.; Kleebe,
H-J.;
Wang, X.; Jacobson, A. J.; Stemmer, S., 2003,
Synthesis and characterization of mixed-valence
barium titanates.
Philosophical Magazine, 83, 165-178.
Wang, X.; Huang, J.; Jacobson, A. J., 2002, [(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4
(USH-8): An Organically Templated
Open-Framework Uranium Silicate.
Journal of the American Chemical Society,, 124, 15190-15191. [PDF]
Huang, J.; Wang, X.; Liu, L.; Jacobson, A. J., 2002,
Synthesis and characterization of an open
framework vanadium silicate (VSH-16Na).
Wang, X.; Liu, L.; Jacobson, A. J., 2002, Open-Framework
and Microporous Vanadium Silicates.
Journal of the American Chemical Society, 124,
7812-7820. [PDF]
Wang, X.; Huang, J.; Liu, L.; Jacobson, A. J., 2002, The novel
open-framework uranium silicates
Na2(UO2)(Si4O10)
·2.1H2O (USH-1) and RbNa(UO2)(Si2O6)·H2O
(USH-3).
J. Mater. Chem., 12, 406-410.
Wang, X.; Liu, L.; Jacobson, A. J., 2002, Hydrothermal synthesis and structures of the
novel niobium
phosphates Ba2[NbOF(PO4)2]
and Ba3[Nb3O3F(PO4)4(HPO4)](H2O)7..
J. Mater. Chem., 12, 1824-1827.
Whitfield, T.; Zheng, L-M; Wang, X.;
Jacobson, A. J., 2001, Syntheses and characterization of
Co(pydc)(H2O)2 and Ni(pydc)(H2O)
(pydc = 3,5-pyridinedicarboxylate).
Wang, X; Liu, L; Jacobson, A.
J., 2001, The novel open-framework vanadium silicates
K2(VO)(Si4O10)·H2O
(VSH-1) and Cs2(VO)(Si6O14)·3H2O
(VSH-2),
Angew. Chem.
Int. Ed. Engl. 40, 2174-2176.
Wang, X; Jacobson, A. J., 2001,
Synthesis of large ZSM-5 crystals under high pressure,
Mater. Res. Soc. Symp. Proc.
, 658 (Solid-State
Chemistry of Inorganic Materials III), GG8.1.1-6. [PDF]
Wang, X; Liu, L.; Zhang, G.; Jacobson, A. J., 2001, An
extended chain structure formed by covalently
linking polyoxovanadate cages with tetrahedral six rings.
J. Chem. Soc., Chem. Commun.,
2001, 2472-2473.
Zheng, L-M, Wang, X; Wang, Y,
Jacobson, A. J., 2001 ,Syntheses and characterization of
Co2(4,4’-bipy)2(V4O12
),Co(pz)(VO3)2 and Co2(2-pzc)(H2
O)(VO3)3(4,4’-bipy = 4,4’-bipyridine,
pz = pyrazine, 2-pzc = 2-pyrazinecarboxylate),
J. Mater. Chem. 11, 1100-1105.
Zheng, L-M, Wang,
Y; Wang, X; Korp, J. D.; Jacobson, A.J., 2001, Anion-directed
Crystallization of
Coordination Polymers: Syntheses and Characterization of Cu 4(2-pzc)4(H2O)8(Mo8O
26)·2H2Oand
Cu3(2-pzc)4(H2O)2 (V10O28H4)·6.5H2O(2-pzc
= 2-pyrazinecarboxylate),
Inorganic Chem., 40, 1380-1385.
Zheng, L-M, Whitfield,
T.; Wang, X.; Jacobson, A. J., 2000, Hybrid Coordination
Polymer-Metal Oxide
Compounds with Chiral Structures,
Angew. Chem. Int. Ed. Engl. 39, 4528-4531.
Wang, X; Liu, L; Cheng, H; Ross, K; Jacobson, A. J., 2000,Synthesis
and crystal structures of
[H3N(CH2)2NH3
]NbMOF(PO4)2(H2O)2, M=Fe,Co
and
[H3N(CH2)2NH3
]Ti(Fe0.9Cr0.1)(F1.3O0.7)(H
0.3PO4)2(H2O)2,
J. Mater. Chem., 10, 1203-1208.
Wang, X; Liu, L; Jacobson, A. J., 2000,Hydrothermal
synthesis and structures of Ba3(NbO)2(PO4 )4 and
Co3(NbO)2(PO4)4(H
2O)10,
J. Mater. Chem., 10, 2774-2779.
Wang, X; Liu, L.; Cheng, H.; Ross, K.; Jacobson, A. J., 2000
,Synthesis and crystal structures of
yttrium sulfates Y(OH)(SO4), Y(SO4 )F,
YNi(OH)3(SO4)-II and Y2Cu(OH)3
(SO4)2F(H2O),
Solid State Sciences, 2, 111-120.
Wang, X; Liu, L; Jacobson, A.
J., 2000,Hydrothermal synthesis and crystal structures of
[(CH3NH3)0.5(NH4 )1.5]Sb8S13.2.8H2Oand
Rb 2Sb8S13.3.3H2O,
J. Solid State Chem., 155, 409-416.
Zheng, L-M.; Wang, X.; Jacobson, A. J., 2000,
Two- and three-dimensional mixed-valence Cu(I)-Cu(II)
coordination polymers: syntheses and characterization of a -, b-[Cu2X(C
5H3N2O2)2(H2
O)](X=Cl, Br),
J. Solid State Chem., 152, 174-182.
Wang, X., 2000, Preparation and properties
of a group of nanoporous materials with
photo-semiconducting
host structures, Materials Science and Engineering (材料科学与工程),
18, No.z2, 556-561.
Wang, X; Liu, L.; Cheng, H.; Jacobson, A. J., 1999, The
synthesis and single crystal structure of an amino acid
intercalated layered niobium phosphate: [NbOPO4] 4(H3NCH2COOH)2(H2PO
4)(OH, F),
J. Chem. Soc., Chem. Commun.,
1999, 2531-2532.
Wang, X.; Liebau, F., 1999, An investigation of microporous
cetineite-type phases
A6[B12O18][CX3] 2[Dx(H2O,OH,O)6-y],II.
Crystal structures and their changes with
chemical composition,
Zeitschr. Kristallogr., 214, 820-834.
Wang, X.; Liu, L.; Jacobson, A. J., 1999, Synthesis and
structures of yttrium transition metal
sulfates YM(OH)3(SO4), M
=Ni,Cu,
J. Solid State Chem., 147, 641-646.
Wang, X.; Jacobson, A. J., 1999, Crystal structure of the
microporous titanosilicate ETS-10
refined from single crystal X-ray diffraction data,
J. Chem. Soc., Chem. Commun.,
1999, 973-974.
Niu,
T.; Wang, X.; Jacobson, A. J., 1999, A three-dimensional coordination
polymer with an
expanded NbO structure,
Angew. Chem. Int. Ed. Engl. 38, 1934-1937.
Wang, X.; Liu, L.; Jacobson, A. J.; Ross, K., 1999,Electrochemical-hydrothermal synthesis and
structure of [N(CH3)4]2[Co(H
2O)4V12O28],
J. Mater. Chem., 9, 859-862.
Liu, L.; Wang, X.; Bontchev, R.; Ross, K.; Jacobson, A. J., 1999,Influence
of reaction conditions on the
electrochemical-hydrothermal synthesis of two ammonium vanadium
phosphates:
(NH4)2VO(HPO4)2.H
2Oand (NH4)2VO(V0.88P1.12 O7),
J. Mater. Chem., 9, 1585-1590.
Do J.; Wang, X.; Jacobson, A. J., 1999, Hydrothermal synthesis
and structures of two tetramethylammounium
iron molybdates (TMA)2FeMo6O20
and (TMA)2[Fe(H2O)6]Mo8O 26,
J. Solid State Chem., 143, 77-85.
Wang, X.; Liu, L.; Bontchev, R.; Jacobson, A. J., 1998,Electrochemical-hydrothermal synthesis
and structure determination of a layered mixed-valence oxide: BaV7O16·nH2O,
J. Chem. Soc., Chem. Commun.,
1998, 1009-1010.
Wang, X.; Liu, L.; Jacobson, A. J., 1998,Electrochemical-hydrothermal
synthesis and structural
characterization of Zn2(OH)VO4,
Z. Anorg. Allg. Chem., 624, 1977-1981.
Wang, X.; Jacobson, A. J.; Liebau, F., 1998, Hydrothermal
synthesis and crystal structure of
[(CH3NH3)1.03K2.97
]Sb12S20·1.34H2O,
J. Solid State Chem., 140, 387-395.
Wang, X.; Jacobson, A. J., 1998, Synthesis and crystal
structure of Sr10[Sb7O13(OH)]2[SbSe
3]2Se·2H2O,
J. Solid State Chem., 140, 134-139.
Wang, X.; Liebau, F., 1998, An investigation of microporous
cetineite-type phases
A6[B12O18][CX3] 2[Dx(H2O,OH,O)6-y],
I. The cetineite structure field,
Eur. J. Solid State Inorg. Chem., 35, 27-37.
Niu, T.; Lu, J.; Wang, X.; Korp, J. D.;
Jacobson, A. J., 1998 ,Syntheses and structural characterization
of two three-dimensional polymers: [{(n-C4H9
)3Sn}3M(CN)6](M=Fe,Co),
Inorg. Chem., 37, 5324-5328.
Starrost, F.; Krasovskii, E. E.; Schattke, W.;
Jockel, J.; Simon, U., Wang,X.; Liebau, F., 1998,
Electronic structure of a novel class of nanoporous materials,
Phys. Rev. Lett., 80, 3316-3319.
Simon, U., Schüth, F., Schunk, S., Wang, X.; Liebau, F., 1997,K3Sb7O9Se3·3H
2O: The first
crystalline nanoporous material with a photo-semiconducting host
structure,
Angew. Chem., Int. Ed. Engl., 36, 1121-1124.
Wang, X.; Liebau, F., 1996, Studies on bond valences and
atomic valences, I. Correlation between
bond valence and bond angles in Sb(III) chalcogen compounds: the influence of lone electron pairs,
Acta Crystallogr.B,
52, 7-15.
Wang, X.; Liebau, F., 1996, Influence of lone-pair electrons
of cations on bond-valence parameters,
Zeitschr. Kristallogr., 211, 437-439.
Wang, X., 1995, Novel nanoporous thioantimonates(III):syntheses
and probable structural series, in
Proceedings of International Symposium on Zeolites in China
,ed. Xu Q., 2, 65-71.
Wang X., 1995, Crystal structures of oxoselenoantimonates(III)
of sodium and rubidium,
Na6(Sb12O18)(SbSe3 )2(Na1.86Sb0.14)((OH)2.28(H
2O)4.02)and Rb6(Sb12O18
)(SbSe3)2Sb0.22((OH)0.66(H 2O)3.48),
Zeitschr. Kristallogr., 210, 693-694.
Wang, X., 1995, Synthesis and crystal structure of a new
microporous thioantimonate(III)
[H3N(CH2)3NH3]Sb
10S16,
Eur. J. Solid State Inorg. Chem., 32, 303-312.
Wang, X.; Liebau, F., 1994, Synthesis and structure of [CH
3NH3]2Sb8S13: a nanoporous
thioantimonate(III) with a
two-dimensional channel system,
J. Solid State Chem., 111, 385-389. [PDF]
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