Influence of Ligand Geometry on the Formation of In-O Chains in MOOFs

        A comparison of the extended structures of 1,2-, 1,3-, and 1,4-InBDC compounds.

The InO₆ octahedra are represented as blue polyhedra.

Octahedral Tilting in MM'X4 Metal Organic Layer Structures

In compounds 1 and 2, water molecules (light blue) are present between the layers and are hydrogen bonded to them.

For monoclinic AlOHBDC, pseudo-orthorhombic projections are shown.

Tossing and Turning

 

Schematic representation of the structural transformation that occurs upon desorption /adsorption of pyridine molecules.

Schematic representation of the structural transformation upon guest exchange in the Ga(OH)BDC framework.

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