Reaction of Building Stones with Atmospheric Pollutants

We have investigated the reaction of building stones with sulfur dioxide-containing atmosphere. This is a joint program with the Materials Research Program of the National Center for Preservation Training and Technology of the National Park Service.
Two building stones are currently under investigation:
The Cretaceous Walnut Formation limestone quarried from near Austin TX.
This building stone is used prominently at the University of Houston.
A volcanic rock from which the Catedral de Mexico, Mexico City is built.
The building stones were imaged using electron microprobe back-scattered and x-ray imaging. They were then exposed to an atmosphere containing ~100 ppm sulfur dioxide with 75% humidity at 25ºC for two weeks. This was performed at the NCPTT through the offices of Dr. Mary Striegel. The stones were then re-imaged in order to find which regions of the stones were preferentially altered by the sulfur dioxide and whether sulfates were precipitated in the samples.
Research conducted by Javier Pruneda, senior undergraduate Dept. of Chemistry, U. of H.

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Last modified: Feb 2, 1999